A couple members of the GA staff have their heads buried in their new PlayStation VR headsets like the rest of the PS4 gaming community, so we'll definitely have some coverage in the somewhat near future. We promise! We're currently swimming in VR-enabled titles to work through.
If you were a little put-off because most of the pre-orders were gobbled up as soon as they became available, that's no longer the case post-launch. Amazon and a number of retailers have either the core headset or the launch bundle available right now.
If you want to see what the setup process is like, whether or not you've picked up a headset at this point, make sure to spend some time with the video tutorial below. For any other questions or concerns, Sony has a detailed PlayStation VR: The Ultimate FAQ to refer to.
PlayStation VR Set Up Tutorial: